Mercurial possibilities: determining site distributions in Cu2HgSnS4 using 63/65Cu, 119Sn, and 199Hg solid-state NMR spectroscopy-Reference-Cited by-同舟云学术

Mercurial possibilities: determining site distributions in Cu₂HgSnS₄ using ^63/65Cu, ¹¹⁹Sn, and ¹⁹⁹Hg solid-state NMR spectroscopy

Published:2022 Issue:39 Volume:24 Page:24306-24316
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bhattacharya Amit¹,Mishra Vidyanshu¹^ORCID,Tkachuk Dylan G.¹,Mar Arthur¹^ORCID,Michaelis Vladimir K.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada

Abstract

Site distribution of Cu (2a, 2c, or 4d) can vary from Cu2ZnSnS4 to Cu2HgSnS4. Leveraging the analytical capabilities of 65Cu solid-state NMR spectroscopy, we solved the site distribution ambiguity between two reported structural models.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Research Chairs

Canada Foundation for Innovation

Government of Alberta

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP02432B

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