Allylic alkylation of co-ordinated cyanide; the synthesis and X-Ray crystal structure of trans-[Mn(CO)(CNCH2CMe = CH2)(dppm)2][PF6]·thf (dppm = Ph2PCH2PPh2, thf = tetrahydrofuran)-Reference-Cited by-同舟云学术

Allylic alkylation of co-ordinated cyanide; the synthesis and X-Ray crystal structure of trans-[Mn(CO)(CNCH2CMe = CH2)(dppm)2][PF6]·thf (dppm = Ph2PCH2PPh2, thf = tetrahydrofuran)

Published:1991 Issue:7 Volume: Page:1851-1854
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Connelly Neil G.,Orpen A. Guy,Rosair Georgina M.,Worth Gillian H.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910001851

Reference12 articles.

1. Allylic alkylation of complexed cyclo-octatetraene (cot)via the reaction of [Fe{P(OMe)3}(NO)2(η3-allyl)]+with [M(CO)3(η4-cot)](M = Fe or Ru) derivatives; X-ray structure of [Ru(CO)2(PPh3)(η2,η3-C8H8R)][PF6]·0.5CH2Cl2[R = CH2C(Me)CH2]

2. Allylation of cobalt-co-ordinated cyclo-octatetraene by the [Fe{P(OMe)3}(NO)2(η3-allyl)]+cation: ring closure to 1,2,3,3a-tetrahydropentalenyl derivatives and the X-ray structure of [Co(η5-C8H8R)(η-C5Me5)][PF6][R = CH2C(Me)CH2]

3. Reaction of [Rh(η4-cot)(η-C5H5)](cot = cyclo-octatetraene) with [Fe{P(OMe)3}(NO)2(η3-CH2CHCH2)]+: allylic alkylation of a cyclopentadienyl ring

4. The reversible one-electron oxidation of trans-[Mn′L(CO)(Ph2PCH2PPh2)2]z+: synthesis and characterisation of stable manganese(II) derivatives

5. Supplement. Tables of bond lengths determined by X-ray and neutron diffraction. Part 2. Organometallic compounds and co-ordination complexes of the d- and f-block metals

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