Allylic alkylation of complexed cyclo-octatetraene (cot)via the reaction of [Fe{P(OMe)3}(NO)2(η3-allyl)]+with [M(CO)3(η4-cot)](M = Fe or Ru) derivatives; X-ray structure of [Ru(CO)2(PPh3)(η2,η3-C8H8R)][PF6]·0.5CH2Cl2[R = CH2C(Me)CH2]-Reference-Cited by-同舟云学术

Allylic alkylation of complexed cyclo-octatetraene (cot)via the reaction of [Fe{P(OMe)3}(NO)2(η3-allyl)]+with [M(CO)3(η4-cot)](M = Fe or Ru) derivatives; X-ray structure of [Ru(CO)2(PPh3)(η2,η3-C8H8R)][PF6]·0.5CH2Cl2[R = CH2C(Me)CH2]

Published:1990 Issue:4 Volume: Page:1291-1300
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Connelly Neil G.,Gilbert Mark,Orpen A. Guy,Sheridan John B.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900001291

Reference29 articles.

1. New rules of selectivity: allylic alkylations catalyzed by palladium

2. Iron-promoted allylic alkylation: regiochemical, stereochemical, and mechanistic aspects

3. Electrophilie du ligande η3-allylique de complexes η3-allyl-dicarbonyl-nitrosyl-fer

4. Stereo- and regio-specific CC bond formation via the coupling of electrophilic and nucleophilic organotransition-metal complexes: The x-ray crystal structure of [Ru(CO)2(PPh3)(η2,η3-C8H8R)][PF6]·0.5CH2Cl2 (R = CH2C(Me)CH2)

5. Synthesis of [Fe(η4-C8H8)(CO)2L][L = MeNC, PriNC, ButNC, PhNC, 2,6-Me2C6H3NC, or P(OMe)3] and proof of the applicability of the Woodward–Hoffmann rules to the fluxionality of [Fe(η4-C8H8)(CO)2(CNPri)]

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3. Complexes of Ruthenium and Osmium Containing η2–η6 Hydrocarbon Ligands: (iii) Complexes Containing Six-, Seven- and Eight-membered Rings;Comprehensive Organometallic Chemistry II;1995

4. Mononuclear Iron Compounds with η1–η6 Hydrocarbon Ligands;Comprehensive Organometallic Chemistry II;1995

5. Annual survey of ruthenium and osmium for the year 1990;Journal of Organometallic Chemistry;1993-09