Tunable mono- and di-methylation of amines with methanol over bimetallic CuCo nanoparticle catalysts

Author:

Li Ke-Ming12,Zhang Qi3ORCID,Xu Zhong-Ming2,Chen Ran2,Liu Tian-Tian2,Luo Jin-Yue2,Wu Yang-Wen1ORCID,Huang Yao-Bing12ORCID,Lu Qiang1ORCID

Affiliation:

1. National Engineering Laboratory for Biomass Power Generation Equipment, School of New Energy, North China Electric Power University, Beijing 102206, P. R. China

2. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China

3. Anhui Province Key Lab of Aerospace Structural Parts Forming Technology and Equipment, Institute of Industry & Equipment Technology, Hefei University of Technology, Hefei 230009, China

Abstract

Heterogeneous non-noble bimetallic CuCo nanoparticle catalysts for selective N-monomethylation and N,N-dimethylation reactions under base-free conditions, offering >50 examples from aromatic/aliphatic amines, nitrocompounds and different alcohols.

Funder

Qinglan Project of Jiangsu Province of China

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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