Photoredox/Bismuth Relay Catalysis Enabling Reductive Alkylation of Nitroarenes with Aldehydes-Reference-Cited by-同舟云学术

Photoredox/Bismuth Relay Catalysis Enabling Reductive Alkylation of Nitroarenes with Aldehydes

Published:2024-06-21 Issue:40 Volume:30 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Li Jinlian¹²,Chen Xing³,Xie Shenxia²,Wang Huabing¹,Mo Jiayu²,Huang Huawen³^ORCID

Affiliation:

1. Guangxi Key Laboratory of Enhanced Recovery after Surgery for Gastrointestinal Cancer Clinical Laboratory Center Department of Clinical Laboratory The First Affiliated Hospital of Guangxi Medical University Shuangyong Road 6 530021 Nanning P. R. China.

2. Department Guangxi Key Laboratory of Bioactive Molecules Research and Evaluation School of Pharmacy Guangxi Medical University Shuangyong Road 22 530021 Nanning P. R. China.

3. College of Chemistry Xiangtan University Xiangtan 411105 P. R. China.

Abstract

AbstractThe effective transition metal‐free photoredox/bismuth dual catalytic reductive dialkylation of nitroarenes with benzaldehydes has been reported. The nitroarene reduction through visible light‐driven photoredox catalysis was integrated with subsequent reductive dialkylation of anilines under bismuth catalysis to enable the cascade reductive alkylation of nitroarenes with carbonyls. Salient features of this relay catalysis system include mild reaction conditions, no requirement for transition metal catalysts, easy handling, step‐economy, and high selectivity.

Funder

Ministry of Science and Technology of the People's Republic of China

Postdoctoral Research Foundation of China

Publisher

Wiley

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5. Reduction‐Specified Coupling Reactions of Nitroarenes by Heterogeneous Cobalt Catalysis