Methanol dimer formation drastically enhances hydrogen abstraction from methanol by OH at low temperature-Reference-Cited by-同舟云学术

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Methanol dimer formation drastically enhances hydrogen abstraction from methanol by OH at low temperature

Published:2016 Issue:32 Volume:18 Page:22712-22718
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Siebrand Willem¹²³,Smedarchina Zorka¹²³,Martínez-Núñez Emilio⁴⁵⁶⁷,Fernández-Ramos Antonio⁴⁵⁶⁷

Affiliation:

1. National Research Council of Canada

2. Ottawa

3. Canada

4. Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) e Departamento de Química Física

5. Universidade de Santiago de Compostela

6. 15782 Santiago de Compostela

7. Spain

Abstract

The kinetics of the reaction of methanol with hydroxyl radicals is revisited in light of reported new kinetic data, measured in cold expansion beams.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04173F

Reference36 articles.

1. Theoretical study on the kinetics for OH reactions with CH3OH and C2H5OH

2. Hydrogen-atom abstraction from methanol by hydroxyl radical

3. Kinetics of the reactions of HO with methanol (210–351 K) and with ethanol (216–368 K)

4. Accelerated chemistry in the reaction between the hydroxyl radical and methanol at interstellar temperatures facilitated by tunnelling

5. Chemistry of Star-Forming Regions

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