Thiolate complexes of osmium(IV): preparation of [Os(SR)4(PR′3)](R = C6F5, C6F4H-4, C6H4F-4 or Ph, R′= Ph; R = C6F5or C6F4H-4, R′3= Me2Ph) and [OsCl(SC6F5)2(SC6H4X-3)(PMe2Ph)](X = F or CF3): crystal structures of [Os(SC6F4H-4)4(PPh3)] and [OsCl(SC6F5)2(SC6H4CF3-3)(PMe2Ph)]-Reference-Cited by-同舟云学术

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Thiolate complexes of osmium(IV): preparation of [Os(SR)4(PR′3)](R = C6F5, C6F4H-4, C6H4F-4 or Ph, R′= Ph; R = C6F5or C6F4H-4, R′3= Me2Ph) and [OsCl(SC6F5)2(SC6H4X-3)(PMe2Ph)](X = F or CF3): crystal structures of [Os(SC6F4H-4)4(PPh3)] and [OsCl(SC6F5)2(SC6H4CF3-3)(PMe2Ph)]

Published:1994 Issue:13 Volume: Page:1819-1824
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Arroyo Maribel,Chamizo Jose A.,Hughes David L.,Richards Raymond L.,Roman Patricia,Sosa Plinio,Torrens Hugo

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1994/DT/DT9940001819

Reference16 articles.

1. Thiolato-complexes of the transition metals

2. RuX = C (X  F or H) interactions in complex compounds. Preparation and crystal structures of [) (SC6F5)2(PMe2Ph)2] and [-2)(C6H5)22]

3. Dinitrogen complexes of osmium(II) with thiolate co-ligands: X-ray structure of mer-[OsCl(SC6F5)(N2)(PMe2Ph)3]

4. A d4-thiolato–dinitrogen complex. The synthesis and crystal structure of [Re(N2)(SC6H2-2,4,6-Pri3)3(PPh3)]

5. Thiolate complexes of osmium(III) with tertiary phosphines and their dicarbonyl derivatives of osmium(II): X-ray crystal structure of trans,trans,trans-[Os(SC6F5)2(CO)2(PEt2Ph)2]

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1. Fluorinated‐Thiolate Osmium(III) and Osmium(IV) Complexes Bearing N,N‐diethyldithiocarbamate and Substituted Phosphines. Synthesis, Crystal Structures and DFT‐Studies;Helvetica Chimica Acta;2024-08-26

2. Exploring the persistence of the fluorinated thiolate 2,3,5,6-S(C₆F₄H-4) motif to establish π_F–π_F stacking in metal complexes: a crystal engineering perspective;Dalton Transactions;2024

3. Tetrakis(2,3,5,6-tetrafluorobenzenethiolato-κS)(triphenylphosphane-κP)osmium(IV): a monoclinic polymorph;IUCrData;2019-12-06

4. Five-coordinate fluorobenzothiolate osmium(IV) complexes [Os(SRF)4(PR3)] (RF=C6F4H-4, R3=Ph2(C6F5); RF=C6F4H-4, R3=(OPh)3; RF=C6F5, R3=(OPh)3): Single-crystal structures and solution structural characterization;Polyhedron;2011-04

5. Chloridotris(pentafluorobenzenethiolato-κS)[tris(4-fluorophenyl)phosphine-κP]osmium(IV);Acta Crystallographica Section E Structure Reports Online;2010-03-31

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