Exploring the persistence of the fluorinated thiolate 2,3,5,6-S(C6F4H-4) motif to establish πF–πF stacking in metal complexes: a crystal engineering perspective-Reference-Cited by-同舟云学术

Exploring the persistence of the fluorinated thiolate 2,3,5,6-S(C₆F₄H-4) motif to establish π_F–π_F stacking in metal complexes: a crystal engineering perspective

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jaime-Adán Everardo¹^ORCID,Germán-Acacio Juan Manuel²^ORCID,Páez-Franco José Carlos²^ORCID,Lara Victor H.³,Reyes-Marquez Viviana⁴^ORCID,Morales-Morales David¹^ORCID

Affiliation:

1. Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Ciudad de México, C. P. 04510, Mexico

2. Red de Apoyo a la Investigación, Universidad Nacional Autónoma de México-CIC, Instituto Nacional de Ciencias Médicas y Nutrición SZ, C. P.14000, Ciudad de México, Mexico

3. Universidad Autonoma Metropolitana, Iztapalapa, Av. San Rafael Atlixco No. 186, Col. Vicentina, 09340 Ciudad de México, Mexico

4. Departamento de Ciencias Químico-Biológicas, Universidad de Sonora, Luis Encinas y Rosales s/n, Hermosillo C.P. 83000, Sonora, Mexico

Abstract

The relevance of the fluorinated thiolate 2,3,5,6-S(C6F4H-4) to serve as a reliable motif for the construction of πF–πF stacking interactions in a series of metal complexes in the solid state for its application in crystal engineering is Illustrated.

Funder

Consejo Nacional de Humanidades, Ciencias y Tecnologías

Dirección General de Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01978D

Reference95 articles.

1. J. W.Steed and J. L.Atwood , Supramolecular Chemistry , Wiley , 2009

2. Crystal engineering, Where from? Where to?

3. G. R.Desiraju , Crystal Engineering: The Design of Organic Solids , Elsevier , Amsterdam , 1989

4. E. R. T.Tiekink , J.Vittal and M.Zaworotko , Organic Crystal Engineering: Frontiers in Crystal Engineering , John Wiley & Sons , 2010

5. Covalent Organic Frameworks: Design, Synthesis, and Functions