Synthesis of stereodiblock polyisoprene consisting of cis-1,4 and trans-1,4 sequences by using a neodymium catalyst: change of the stereospecificity triggered by an aluminum compound-Reference-Cited by-同舟云学术

Synthesis of stereodiblock polyisoprene consisting of cis-1,4 and trans-1,4 sequences by using a neodymium catalyst: change of the stereospecificity triggered by an aluminum compound

Published:2016 Issue:6 Volume:7 Page:1239-1243
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Tanaka Ryo¹²³⁴,Yuuya Kaede¹²³⁴,Sato Hiroki¹²³⁴,Eberhardt Peter¹²³⁴,Nakayama Yuushou¹²³⁴,Shiono Takeshi¹²³⁴

Affiliation:

1. Graduate School of Engineering

2. Hiroshima University

3. Higashi-hiroshima

4. 739-8527 Japan

Abstract

The synthesis of stereodiblock polyisoprene which consists ofcis-1,4 andtrans-1,4 sequences was achieved by using a neodymium catalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C5PY01872B

Reference30 articles.

1. Discrete, Multiblock Isotactic–Atactic Stereoblock Polypropene Microstructures of Differing Block Architectures through Programmable Stereomodulated Living Ziegler–Natta Polymerization

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3. Synthesis and characterization of iPP-sPP stereoblock produced by a binary metallocene system

4. rac-[Ethylidene(1-.eta.5-tetramethylcyclopentadienyl)(1-.eta.5-indenyl)]dichlorotitanium and its homopolymerization of propylene to crystalline-amorphous block thermoplastic elastomers

5. Oscillating Stereocontrol: A Strategy for the Synthesis of Thermoplastic Elastomeric Polypropylene

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