Role of conductive binder to direct solid–electrolyte interphase formation over silicon anodes

Author:

Browning Katie L.12345ORCID,Browning James F.6784ORCID,Doucet Mathieu6784ORCID,Yamada Norifumi L.910111213ORCID,Liu Gao1415164ORCID,Veith Gabriel M.5784ORCID

Affiliation:

1. Department of Materials Science and Engineering

2. University of Tennessee

3. Knoxville

4. USA

5. Chemical Sciences Division

6. Neutron Scattering Division

7. Oak Ridge National Laboratory

8. Oak Ridge

9. Neutron Science Laboratory

10. High Energy Accelerator Research Organization

11. 203-1 Shirakata, Tokai

12. Naka

13. Japan

14. Electrochemistry Division

15. Lawrence Berkeley National Laboratory

16. San Francisco

Abstract

With the use of in situ neutron reflectometry (NR) we show how the addition of an electronically conductive polymeric binder, PEFM, mediates the solid–electrolyte interphase (SEI) formation and composition on an amorphous Si (a-Si) electrode as a function of the state-of-charge.

Funder

Vehicle Technologies Program

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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