On the selective cleavage of nitrous oxide by metal–amide complexes
Author:
Affiliation:
1. Research School of Chemistry
2. Australian National University
3. Canberra, Australia
4. School of Chemistry
5. University of Tasmania
6. Hobart, Australia
Abstract
The remarkable selective cleavage of nitrous oxide by metal–amide systems, involving a bimetallic mechanism, has been investigated using computational methodology and rationalized on the basis of the interplay of structural and bonding factors.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53062K
Reference16 articles.
1. Binding and Activation of N2O at Transition-Metal Centers: Recent Mechanistic Insights
2. Y.-R. Luo , Comprehensive Handbook of Chemical Bond Energies , Taylor and Francis , Boca Raton , 2007
3. Cleavage of the Nitrous Oxide NN Bond by a Tris(amido)molybdenum(III) Complex
4. On the Origin of Selective Nitrous Oxide N−N Bond Cleavage by Three-Coordinate Molybdenum(III) Complexes
5. Does Reaction of Three-Coordinate Molybdenum(III) with N2O Proceed via the Same Mechanism as with N2? A Theoretical Study
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