Direct detection of molecular hydrogen upon p- and n-doping of organic semiconductors with complex oxidants or reductants

Author:

Pallini Francesca1ORCID,Mattiello Sara1ORCID,Manfredi Norberto1ORCID,Mecca Sara1ORCID,Fedorov Alexey2,Sassi Mauro1ORCID,Al Kurdi Khaled3,Ding Yi-Fan4,Pan Chen-Kai4,Pei Jian4ORCID,Barlow Stephen35ORCID,Marder Seth R.356,Nguyen Thuc-Quyen7ORCID,Beverina Luca1ORCID

Affiliation:

1. Department of Materials Science, Università di Milano-Bicocca, via Cozzi 55, 20125 Milan, Italy

2. CNR-IFN, L-NESS, via Anzani 42, I-22100 Como, Italy

3. School of Chemistry and Biochemistry, Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA

4. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center of Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

5. Renewable and Sustainable Energy Institute, University of Colorado Boulder, Boulder, CO 80303, USA

6. Department of Chemical and Biological Engineering, Department of Chemistry, Materials Science and Engineering Program, University of Colorado Boulder, Boulder, CO 80303, USA

7. Center for Polymers and Organic Solids, Department of Chemistry & Biochemistry, University of California, Santa Barbara, CA 93106-9510, USA

Abstract

The formation of molecular hydrogen is detected for the first time in the uncatalysed doping of a variety of semiconductors with molecular dopants.

Funder

U.S. Department of Energy

Ministero dell'Università e della Ricerca

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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