Nickel-catalyzed cross-coupling of <i>N</i>-acyl benzotriazoles with oxiranes and oxetanes for the synthesis of β-haloethyl and γ-halopropyl esters-Reference-Cited by-同舟云学术

Nickel-catalyzed cross-coupling of N-acyl benzotriazoles with oxiranes and oxetanes for the synthesis of β-haloethyl and γ-halopropyl esters

Published:2023 Issue:20 Volume:10 Page:5158-5163
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Bai Jin¹^ORCID,Qu Erdong¹,Li Shangzhang¹,Zhu Riqian¹,Deng Qinyue¹^ORCID,Li Wanfang¹^ORCID

Affiliation:

1. School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai, 200093, P. R. China

Abstract

Ni-catalyzed cross-coupling of N-acyl benzotriazoles, oxiranes/oxetanes and trimethylsilyl halides afforded β- and γ-halo esters with good yields and wide substrate scope. Preliminary mechanistic studies point to a σ-bond metathesis pathway.

Funder

National Natural Science Foundation of China

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00973D

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