Green catalytic conversion of bio-based sugars to 5-chloromethyl furfural in deep eutectic solvent, catalyzed by metal chlorides
Author:
Affiliation:
1. College of Energy
2. Xiamen University
3. Xiamen
4. PR China
Abstract
5-Chloromethylfurfural (5-CMF) was effectively prepared from fructose and other carbohydrates in a biphasic reaction system, which was composed of methyl isobutyl ketone (MIBK) and deep eutectic solvent (DES) with catalyst of AlCl3·6H2O.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA00267F
Reference15 articles.
1. The Path Forward for Biofuels and Biomaterials
2. Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose
3. Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals
4. 5-(Chloromethyl)furfural is the New HMF: Functionally Equivalent But More Practical in Terms of its Production From Biomass
5. Dehydration of Highly Concentrated Solutions of Fructose to 5‐Hydroxymethylfurfural in a Cheap and Sustainable Choline Chloride/Carbon Dioxide System
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