Hydrogen peroxide disproportionation with manganese macrocyclic complexes of cyclen and pyclen-Reference-Cited by-同舟云学术

Hydrogen peroxide disproportionation with manganese macrocyclic complexes of cyclen and pyclen

Published:2020 Issue:7 Volume:7 Page:1573-1582
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Freire David M.¹²³⁴^ORCID,Beeri Debora¹²³⁴^ORCID,Pota Kristof¹²³⁴^ORCID,Johnston Hannah M.¹²³⁴,Palacios Philip¹⁵⁶⁴,Pierce Brad S.¹⁷⁴^ORCID,Sherman Benjamin D.¹²³⁴^ORCID,Green Kayla N.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Texas Christian University

3. Fort Worth

4. USA

5. The University of Texas at Arlington

6. Arlington

7. University of Alabama

Abstract

Pyclen and cylen complexes of manganese show pH dependent catalase activity with improved TOF and TON for the more rigid pyclen derivative. Spectroscopic investigation shows O₂ evolution corresponds with the presence of a μ-O bridged species.

Funder

National Institute of General Medical Sciences

Division of Chemistry

Texas Christian University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QI/C9QI01509D

Reference60 articles.

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