Further insight into the electrocatalytic water oxidation by macrocyclic nickel(ii) complexes: the influence of steric effect on catalytic activity-Reference-Cited by-同舟云学术

Further insight into the electrocatalytic water oxidation by macrocyclic nickel(ii) complexes: the influence of steric effect on catalytic activity

Published:2017 Issue:23 Volume:7 Page:5585-5593
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wang Jia-Wei¹²³⁴⁵^ORCID,Hou Cheng¹²³⁴⁵,Huang Hai-Hua¹²³⁴⁵^ORCID,Liu Wen-Ju¹²³⁴⁵,Ke Zhuo-Feng¹²³⁴⁵^ORCID,Lu Tong-Bu¹²³⁴⁵^ORCID

Affiliation:

1. MOE Key Laboratory of Bioinorganic and Synthetic Chemistry

2. School of Chemistry

3. Sun Yat-Sen University

4. Guangzhou 510275

5. China

Abstract

Macrocyclic nickel(ii) complexes with axially oriented methyl groups can impose a steric effect on the axial position of the in situ formed Ni^III center, which results in higher Ni^III/II oxidation potentials and suppresses the axial coordination of phosphate anions with the Ni^III center.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY01527E

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