The N-atom in [N(PR3)2]+ cations (R = Ph, Me) can act as electron donor for (pseudo) anti-electrostatic interactions-Reference-Cited by-同舟云学术

The N-atom in [N(PR3)2]+ cations (R = Ph, Me) can act as electron donor for (pseudo) anti-electrostatic interactions

Author:

Bauzá Antonio¹²,Frontera Antonio¹²^ORCID,Mooibroek Tiddo J.³⁴⁵,Reedijk Jan⁶⁷⁸⁹¹⁰

Affiliation:

1. Department of Chemistry Universitat de les Illes Balears

2. 07122 Palma (Baleares), Spain

3. School of Chemistry of the University of Bristol

4. Cantock's Close

5. Bristol, UK

6. Leiden Institute of Chemistry

7. Leiden University

8. 2300 RA Leiden, The Netherlands

9. Department of Chemistry

10. College of Science

Abstract

A CSD analysis and DFT study reveal that the nitrogen lone-pair in [N(PPh₃)₂]⁺ is partially intact and involved in intramolecular hydrogen bonding.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

Reference18 articles.

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3. P. D. Beer , P. A.Gale and D. K.Smith , Supramolecular chemistry , Oxford University Press , Oxford , 1999

4. J. W. Steed and J. L.Atwood , Supramolecular chemistry , Wiley , Chichester , 2000

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