Reactions of co-ordinated ligands. Part 55. Molybdenummediated addition of alkynes to cyclooctatetraene; one-electron oxidation and protonation of η3-allyl(η4-1,3-diene)(η-cyclopentadienyl or η5-indenyl) molybdenum complexes, and crystal structures of [Mo(η3,η4-C12H13)(η-C5H5)], [Mo(η2,η4-C14H17)(η-C5H5)][BF4] and [Mo(η2,η4-C12H13)(µMo,C-H)(η5-C9H7)][CF3SO3]-Reference-Cited by-同舟云学术

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Reactions of co-ordinated ligands. Part 55. Molybdenummediated addition of alkynes to cyclooctatetraene; one-electron oxidation and protonation of η3-allyl(η4-1,3-diene)(η-cyclopentadienyl or η5-indenyl) molybdenum complexes, and crystal structures of [Mo(η3,η4-C12H13)(η-C5H5)], [Mo(η2,η4-C14H17)(η-C5H5)][BF4] and [Mo(η2,η4-C12H13)(µMo,C-H)(η5-C9H7)][CF3SO3]

Published:1993 Issue:11 Volume: Page:1747-1759
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Brammer Lee,Dunne Barry J.,Green Michael,Moran Grainne,Orpen A. Guy,Reeve Carolyn,Schaverien Colin J.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930001747

Reference26 articles.

1. Reactions of co-ordinated ligands. Part 54. Synthesis of (1,2,3-η)-trans-butadienyl complexes by deprotonation or desilylation of cationic molybdenum 1,3-diene complexes; formation of η4-vinylketene complexes and crystal structures of [Mo{(1,2,3-η)-trans-CH2CHCCH2}(CO)2(η-C5Me5)], [Mo{η3-CH2CC(Me)CH2CO}(CO)2(η-C5Me5)] and [Mol{η4-CH2CHC(Me)CO}(CO)(η-C5Me5)]

2. Cobalt metallocycles. 6. Preparation and structure of cobaltacyclopentene complexes and their reactions with olefins and acetylenes

3. Reactions of co-ordinated ligands. Part 29. The formation of a 1,3-diene at a molybdenum centre by linking of but-2-yne with an alkene; X-ray crystal structures of [Mo(η2-o-Ph2PC6H4CHCH2)(η2-MeC2Me)(η-C5H5)][BF4] and [Mo(NCMe)(η4-o-MeCHCMe–CHCHC6H4PPh2)(η-C5H5)][BF4]

4. Synthesis and reactivity of cationic alkene–alkyne molybdenum complexes; structural evidence for the formation of an η3,η3-bonded hexatriene ligand by coupling of a co-ordinated alkyne and a 1,3-diene

5. Cyclization via isomerization: a palladium(2+)-catalyzed carbocyclization of 1,6-enynes to 1,3- and 1,4-dienes

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1. Catalytic [6π + 2π]-Cycloaddition of 1,2-Dienes to Bis(cyclohepta-1,3,5-trien-7-yl)alkanes in the Presence of Ti(acac)2Cl2,–Et2AlCl;Russian Journal of Organic Chemistry;2018-06

2. Cobalt(I)-catalyzed [4π+2π] cycloaddition reactions of 1,3-diynes with 1,3,5-cyclooctatriene;Tetrahedron Letters;2017-05

3. Titanium-catalyzed [6π+2π]-cycloaddition of Si-containing alkynes to bis (1,3,5-cycloheptatriene-7-yl)alkanes;Tetrahedron Letters;2017-04

4. η3-Allyl carbonyl complexes of group 6 metals: Structural aspects, isomerism, dynamic behaviour and reactivity;Coordination Chemistry Reviews;2017-03

5. Triphenylcarbenium Tetrafluoroborate;Encyclopedia of Reagents for Organic Synthesis;2011-09-15

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