Lanthanoid coordination prompts unusually distorted pseudo-octahedral Ni<sup>II</sup> coordination in heterodinuclear Ni–Ln complexes: synthesis, structure and understanding of magnetic behaviour through experiment and computation-Reference-Cited by-同舟云学术

Lanthanoid coordination prompts unusually distorted pseudo-octahedral Ni^II coordination in heterodinuclear Ni–Ln complexes: synthesis, structure and understanding of magnetic behaviour through experiment and computation

Published:2023 Issue:30 Volume:52 Page:10402-10414
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dutta Biswarup¹,Guizouarn Thierry²,Pointillart Fabrice²^ORCID,Kotrle Kamil³^ORCID,Herchel Radovan³^ORCID,Ray Debashis¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India

2. Univ. Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, F-35000 Rennes, France

3. Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, 77146 Olomouc, Czech Republic

Abstract

A series of NiII–LnIII dinuclear complexes (Ln = Gd, Tb, Dy, Ho, Er, Yb and Y) have been synthesized and structurally characterized. The complexes involving Kramers lanthanide ions (LnIII = Dy, Er and Yb) are field-induced single-molecule magnets.

Funder

Centre National de la Recherche Scientifique

Université de Rennes 1

H2020 European Research Council

Indian Institute of Technology Kharagpur

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01387A

Reference86 articles.