Dinuclear cobalt complexes with a redox active biphenyl bridging ligand [Co2(BP)(tqa)2](PF6)2 (H4BP = 4,4′-bis(3-tert-butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): structure and magnetic properties-Reference-Cited by-同舟云学术

Dinuclear cobalt complexes with a redox active biphenyl bridging ligand [Co2(BP)(tqa)2](PF6)2 (H4BP = 4,4′-bis(3-tert-butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): structure and magnetic properties

Published:2021 Issue:28 Volume:50 Page:9833-9841
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Suenaga Yusaku¹²³⁴^ORCID,Mibu Takuto¹²³⁴,Okubo Takashi¹²³⁴⁵,Maekawa Masahiko⁵²³⁴^ORCID,Kuroda-Sowa Takayoshi¹²³⁴,Sugimoto Kunihisa⁶⁷⁸⁴⁹^ORCID

Affiliation:

1. Department of Science

2. Kindai University

3. Osaka 577-8502

4. Japan

5. Research Institute of Science and Technology

6. Diffraction & Scattering Division

7. Japan Synchrotron Radiation Research Institute(JASRI)

8. Sayo-gun

9. Institute for Integrated Cell-Material Sciences (iCeMS)

Abstract

[Co₂(BP)(bpqa)₂](PF₆)₂ shows evidence of temperature dependence of the charge distribution, displaying a thermally induced valence tautomeric transition from the lsCo^III-[Cat–Cat]-lsCo^III to hsCo^II-[Sq–Sq]-hsCo^II in both solid and solution states.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00995H

Reference32 articles.

1. Valence Tautomeric Transition Metal Complexes

2. Quinonoid Metal Complexes: Toward Molecular Switches

3. Control of Magnetic Properties through External Stimuli

4. Spin-Crossover Materials , ed. M. A. Halcrow , Wiley , Chichester, U.K. , 2013

5. Solvation effects on the valence tautomeric transition of a cobalt complex in the solid state

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5. Correction: Dinuclear cobalt complexes with a redox active biphenyl bridging ligand [Co2(BP)(tqa)2](PF6)2 (H4BP = 4,4′-bis(3-tert-butyl-1,2-catechol), tqa = tris(2-quinolylmethyl)amine): structure and magnetic properties;Dalton Transactions;2021