Structural stability, optical and thermoelectric properties of the layered RbSn<sub>2</sub>Br<sub>5</sub> halide synthesized using mechanochemistry-Reference-Cited by-同舟云学术

Structural stability, optical and thermoelectric properties of the layered RbSn₂Br₅ halide synthesized using mechanochemistry

Published:2023 Issue:13 Volume:25 Page:1857-1868
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Abia Carmen¹²,López Carlos A.³¹,Gainza Javier¹^ORCID,Rodrigues João Elias F. S.¹⁴^ORCID,Fragoso Brenda⁵,Ferrer Mateus M.⁵,Nemes Norbert M.¹⁶^ORCID,Dura Oscar J.⁷^ORCID,Martínez José Luis¹^ORCID,Fernández-Díaz María Teresa²,Alonso José Antonio¹^ORCID

Affiliation:

1. CSIC, Instituto de Ciencia de Materiales de Madrid, Cantoblanco 28049 Madrid, Spain

2. Institut Laue Langevin, 38042 Grenoble Cedex, France

3. INTEQUI, (UNSL-CONICET) and Facultad de Química, Bioquímica y Farmacia, UNSL, Almirante Brown 1455, 5700, San Luis, Argentina

4. European Synchrotron Radiation Facility (ESRF), 71 Avenue des Martyrs, 38000 Grenoble, France

5. CCAF, PPGCEM/CDTec, Federal University of Pelotas, 96010-610 Pelotas, Rio Grande do Sul, Brazil

6. Departamento de Física de Materiales, Universidad Complutense de Madrid, E-28040 Madrid, Spain

7. Departamento de Física Aplicada, Universidad de Castilla-La Mancha, Ciudad Real, E-13071, Spain

Abstract

In RbSn2Br5 halide, prepared by mechano-chemistry, the 5s2 lone electron pairs of Sn2+ were located from NPD and SXRD data. Among the thermoelectric properties, a huge Seebeck coefficient and an extremely low thermal conductivity are determined.

Funder

Ministerio de Ciencia e Innovación

Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CE/D2CE01488B

Reference63 articles.

1. Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells

2. Kinetically Stable Single Crystals of Perovskite-Phase CsPbI3

3. Direct synthesis of cubic phase CsPbI3 nanowires

4. Crystallization of CsPbBr3 single crystals in water for X-ray detection

5. Highly Stable and Spectrally Tunable Gamma Phase Rb x Cs 1– x PbI 3 Gradient‐Alloyed Quantum Dots in PMMA Matrix through A Sites Engineering

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