Stratification and two glass-like thermal transitions in aged polymer films
Author:
Affiliation:
1. Soft Materials Laboratory
2. Department of Physics
3. Indian Institute of Technology Madras
4. Chennai – 600036
5. India
6. Chemical and Biological Engineering
7. Princeton University
8. Princeton
9. USA
Abstract
Two glass-like thermal transitions and anomalous thermal expansion are observed in stratified and prolonged physically aged polystyrene films.
Funder
Division of Materials Research
Board of Research in Nuclear Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP05726A
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1. Glass transition of polymers in bulk, confined geometries, and near interfaces
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3. Possible origin of thickness-dependent deviations from bulk properties of thin polymer films
4. Dewetting of confined polymer films: an X-ray and neutron scattering study
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