(PhC(NtBu)2Al)2(SiH2)4 six-membered heterocycle: comparable in structure to cyclohexane-Reference-Cited by-同舟云学术

(PhC(NtBu)2Al)2(SiH2)4 six-membered heterocycle: comparable in structure to cyclohexane

Published:2019 Issue:16 Volume:55 Page:2360-2363
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Jiancheng¹²³⁴⁵,Zhong Mingdong⁵⁶⁷,Keil Helena⁵⁶⁷,Zhu Hongping¹²³⁴^ORCID,Herbst-Irmer Regine⁵⁶⁷^ORCID,Stalke Dietmar⁵⁶⁷^ORCID,De Sriman⁸⁹¹⁰^ORCID,Koley Debasis⁸⁹¹⁰^ORCID,Roesky Herbert W.⁵⁶⁷^ORCID

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surface

2. National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters College of Chemistry and Chemical Engineering Xiamen University

3. Xiamen 361005

4. China

5. Institut für Anorganische Chemie, Universität Göttingen

6. 37077 Göttingen

7. Germany

8. Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Kolkata

9. Mohanpur-741 246

10. India

Abstract

A (PhC(NtBu)₂Al)₂(SiH₂)₄ centrosymmetric six-membered heterocycle (LAl)₂(SiH₂)₄ (L = PhC(NtBu)₂) with chair conformation is prepared by reacting disilylene LSi–SiL with alane AlH₃·NEtMe₂. It is comparable in structure to cyclohexane containing four Si and two Al atoms as a core.

Funder

China Scholarship Council

Danmarks Grundforskningsfond

University Grants Commission

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC10124H

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