One silicon atom of bis(silylene) functions as a selective Lewis base under adduct formation with a Lewis acid-Reference-Cited by-同舟云学术

One silicon atom of bis(silylene) functions as a selective Lewis base under adduct formation with a Lewis acid

Published:2023 Issue:18 Volume:52 Page:6175-6179
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ding Yi¹²,Nazish Mohd²^ORCID,Ruth Paul Niklas²,Herbst-Irmer Regine²^ORCID,Stalke Dietmar²^ORCID,Roesky Herbert W.²^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering, State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China

2. Institute of Inorganic Chemistry, Georg-August-Universität Göttingen, Göttingen Tammannstrasse 4, D-37077, Germany

Abstract

We describe the facile and selective one-pot synthetic route to silylene-aluminum and silylene-gallium adducts, in which one silicon atom of bis(silylene) functions as a selective Lewis base under adduct formation with a Lewis acid.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00811H

Reference50 articles.

1. In search of triplet silylenes

2. Theory Predicts Triplet Ground-State Organic Silylenes

3. Stable Silylenes

4. Chemistry of thermally stable bis(amino)silylenes

5. The quest for triplet ground state silylenes

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