The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study-Reference-Cited by-同舟云学术

The “Wanderlust” of Me3Si groups in rare-earth triple-decker complexes: a combined experimental and computational study

Published:2018 Issue:73 Volume:54 Page:10280-10283
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Lorenz Volker¹²³,Liebing Phil⁴⁵⁶⁷^ORCID,Bathelier Adrien⁸⁹¹⁰¹¹¹²,Engelhardt Felix¹²³,Maron Laurent⁸⁹¹⁰¹¹¹²,Hilfert Liane¹²³,Busse Sabine¹²³,Edelmann Frank T.¹²³^ORCID

Affiliation:

1. Chemisches Institut der Otto-von-Guericke-Universität

2. 39106 Magdeburg

3. Germany

4. ETH Zürich

5. Laboratorium für Anorganische Chemie

6. 8093 Zürich

7. Switzerland

8. Université de Toulouse

9. INSA

10. UPS

11. CNRS-UMR5215

12. LPCNO Avenue de Rangueil 135

Abstract

The migration of Me₃Si groups (“Wanderlust”) in rare-earth triple-decker sandwich complexes of the type Ln₂(COT′′)₃ (COT′′ = bis(trimethylsilyl)cyclooctatetraenyl) has been elucidated by a combined experimental and computational study.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC05317K

Reference42 articles.

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4. Uranocene. The First Member of a New Class of Organometallic Derivatives of the f Elements

5. f-BlockAnsaComplexes in the Solid State: [3]Thoro- and [3]Uranocenophanes

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