It's not just the size that matters: crystal engineering of lanthanide-based coordination polymers

Author:

Hauser Adrian1ORCID,Münzfeld Luca1ORCID,Uhlmann Cedric1ORCID,Lebedkin Sergei2,Schlittenhardt Sören2ORCID,Ruan Ting-Ting3,Kappes Manfred M.24ORCID,Ruben Mario253,Roesky Peter W.1ORCID

Affiliation:

1. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131 Karlsruhe, Germany

2. Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

3. Institute of Quantum Materials and Technologies (IQMT), Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

4. Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, D-76131 Karlsruhe, Germany

5. Centre Européen de Science Quantique (CESQ), Institut de Science et d’Ingénierie Supramoléculaires (ISIS, UMR 7006), CNRS-Université de Strasbourg, 8 allée Gaspard Monge BP 70028, 67083 Strasbourg Cedex, France

Abstract

The synthesis of various CotTIPS-based Ln coordination polymers is reported. Different chain polymers were obtained depending on the ionic radii of the lanthanides and the solvent chosen for crystallization. The photophysical and magnetic properties were investigated.

Funder

Deutsche Forschungsgemeinschaft

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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