The influence of LiH on the rehydrogenation behavior of halide free rare earth (RE) borohydrides (RE = Pr, Er)-Reference-Cited by-同舟云学术

The influence of LiH on the rehydrogenation behavior of halide free rare earth (RE) borohydrides (RE = Pr, Er)

Published:2016 Issue:35 Volume:18 Page:24387-24395
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Heere Michael¹²³⁴,Payandeh GharibDoust Seyed Hosein⁵⁶⁷⁸,Frommen Christoph¹²³⁴,Humphries Terry D.¹²³⁴⁹,Ley Morten B.⁵⁶⁷⁸¹⁰,Sørby Magnus H.¹²³⁴,Jensen Torben R.⁵⁶⁷⁸^ORCID,Hauback Bjørn C.¹²³⁴

Affiliation:

1. Physics Department

2. Institute for Energy Technology

3. NO-2027 Kjeller

4. Norway

5. Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry

6. University of Århus

7. DK-8000 Århus C

8. Denmark

9. Department of Physics and Astronomy

10. Max-Planck-Institut für Kohlenforschung

Abstract

The physical mixture of the desorbed Er(BH₄)₃ with 50 wt% of LiH was also investigated upon rehydrogenation. At 400 °C, under 100 bar H₂, the crystalline reaction products, ErH₃ and LiBH₄, appeared during cooling. The presence of LiH improves the crystallinity and rehydrogenation properties.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04523E

Reference45 articles.

1. Experimental and computational studies on solvent-free rare-earth metal borohydridesR(BH4)3(R=Y, Dy, and Gd)

2. Crystal structures and properties of solvent-free LiYb(BH4)4−xClx, Yb(BH4)3 and Yb(BH4)2−xClx

3. Y(BH4)3—an old–new ternary hydrogen store akalearning from a multitude of failures

4. Crystal structure, polymorphism, and thermal properties of yttrium borohydride Y(BH4)3

5. Synthesis, Crystal Structure, and Thermal Properties of the First Mixed-Metal and Anion-Substituted Rare Earth Borohydride LiCe(BH4)3Cl

Cited by 25 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Hydrogen storage in complex hydrides: past activities and new trends;Progress in Energy;2022-06-23

2. New perspectives of functional metal borohydrides;Journal of Alloys and Compounds;2022-03

3. Rare Earth Starting Materials and Methodologies for Synthetic Chemistry;Chemical Reviews;2022-01-31

4. Structural and dynamic studies of Pr(11BH4)3;International Journal of Hydrogen Energy;2021-09

5. Metal Borohydrides beyond Groups I and II: A Review;Materials;2021-05-14