Thorium amidates function as single-source molecular precursors for thorium dioxide-Reference-Cited by-同舟云学术

Thorium amidates function as single-source molecular precursors for thorium dioxide

Published:2021 Issue:40 Volume:57 Page:4954-4957
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Straub Mark D.¹²²³⁴^ORCID,Ouellette Erik T.¹²²³⁴^ORCID,Boreen Michael A.¹²²³⁴^ORCID,Branson Jacob A.¹²²³⁴^ORCID,Ditter Alex⁴²³,Kilcoyne A. L. David⁴²³^ORCID,Lohrey Trevor D.¹²²³⁴^ORCID,Marcus Matthew A.⁴²³,Paley Maria¹²²³,Ramirez José¹²²³,Shuh David K.⁴²³^ORCID,Minasian Stefan G.⁴²³^ORCID,Arnold John¹²²³⁴^ORCID

Affiliation:

1. University of California

2. Berkeley

3. USA

4. Lawrence Berkeley National Laboratory

Abstract

Volatile thorium amidates can be converted to ThO₂ in the absence of an external oxygen source, and the thermal properties of these precursors can be readily tuned by modifying the ligand substituents.

Funder

Lawrence Berkeley National Laboratory

U.S. Department of Energy

National Institutes of Health

National Nuclear Security Administration

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC00867F

Reference46 articles.

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2. M. A. Boreen and J.Arnold , Multiple Bonding in Actinide Chemistry, in the Encyclopedia of Inorganic and Bioinorganic Chemistry , Wiley , 2018

3. Thorium coordination: A comprehensive review based on coordination number

4. The Renaissance of Non-Aqueous Uranium Chemistry

5. Actinide coordination and organometallic complexes with multidentate polyamido ligands

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