On the gelation of humins: from transient to covalent networks

Author:

Cerdan Kenneth1ORCID,Gandara-Loe Jesus2,Arnauts Giel2,Vangramberen Vedran1,Ginzburg Anton3,Ameloot Rob2ORCID,Koos Erin1ORCID,Van Puyvelde Peter1

Affiliation:

1. Department of Chemical Engineering, Soft Matter, Rheology and Technology (SMaRT), KU Leuven, Celestijnenlaan 200J, 3001 Heverlee, Belgium

2. Department of Microbial and Molecular Systems, Centre for Membrane Separation, Adsorption, Catalysis and Spectroscopy, KU Leuven, Celestijnenlaan 200J, 3001 Heverlee, Belgium

3. Department of Chemical Engineering, Soft Matter, Rheology and Technology (SmaRT), Wetenschapspark 27, 3590 Diepenbeek, Belgium

Abstract

Humins’ gel structure combines physical and chemical crosslinks, with temperature dictating their properties. A change from a supramolecular to a covalently crosslinked network is observed, and the resulting stage of polymerization greatly influences material properties.

Funder

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

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