Near-unity electrochemical conversion of nitrate to ammonia on crystalline nickel porphyrin-based covalent organic frameworks-Reference-Cited by-同舟云学术

Near-unity electrochemical conversion of nitrate to ammonia on crystalline nickel porphyrin-based covalent organic frameworks

Published:2023 Issue:1 Volume:16 Page:201-209
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Lv Fang¹²,Sun Mingzi³^ORCID,Hu Yongpan¹²,Xu Jie¹²,Huang Wei¹²,Han Na¹²,Huang Bolong³⁴^ORCID,Li Yanguang¹²⁵^ORCID

Affiliation:

1. Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, 215123, China

2. Jiangsu Key Laboratory for Advanced Negative Carbon Technologies, Soochow University, Suzhou, 215123, China

3. Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China

4. Research Centre for Carbon-Strategic Catalysis, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China

5. Macao Institute of Materials Science and Engineering (MIMSE), MUST-SUDA Joint Research Center for Advanced Functional Materials, Macau University of Science and Technology, Taipa 999078, Macau SAR, China

Abstract

A novel 2D nickel porphyrin-based covalent organic framework is fabricated as an efficient nitrate reduction electrocatalyst that shows a great selectivity of ∼90% under a mild overpotential with a remarkable production rate and turnover frequency.

Funder

Higher Education Discipline Innovation Project

Hong Kong Polytechnic University

National Natural Science Foundation of China

Macau University of Science and Technology

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/EE/D2EE02647C