Reduction-induced facile isomerisation of metallacarboranes: synthesis and crystallographic characterisation of 4-Cp-4,1,2-closo-CoC2B9H11-Reference-Cited by-同舟云学术

Reduction-induced facile isomerisation of metallacarboranes: synthesis and crystallographic characterisation of 4-Cp-4,1,2-closo-CoC2B9H11

Published:2015 Issue:35 Volume:44 Page:15417-15419
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Man Wing Y.¹²³⁴,Rosair Georgina M.¹²³⁴,Welch Alan J.¹²³⁴

Affiliation:

1. Institute of Chemical Sciences

2. Heriot-Watt University

3. Edinburgh

4. UK

Abstract

One-electron reduction of 3-Cp-3,1,2-closo-CoC₂B₉H₁₁ followed by heating to reflux in DME (b.p. 85 °C) induces isomerisation to 4-Cp-4,1,2-closo-CoC₂B₉H₁₁.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02506K

Reference27 articles.

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3. .pi.-Dicarbollyl derivatives of the transition metals. Metallocene analogs

4. Synthesis and/or molecular structures of some simple 2,1,7- and 2,1,12-ruthena- and cobaltacarboranes

5. Crystal structure of a second polymorph of 2-cyclopentadienyl-1,7-dicarba-2-cobalta-closo-dodecaborane(11)

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