Steric versus electronic factors in metallacarborane isomerisation: nickelacarboranes with 3,1,2-, 4,1,2- and 2,1,8-NiC2B9 architectures and pendant carborane groups, derived from 1,1′-bis(o-carborane)-Reference-Cited by-同舟云学术

Steric versus electronic factors in metallacarborane isomerisation: nickelacarboranes with 3,1,2-, 4,1,2- and 2,1,8-NiC2B9 architectures and pendant carborane groups, derived from 1,1′-bis(o-carborane)

Published:2016 Issue:38 Volume:45 Page:15013-15025
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mandal Dipendu¹²³⁴,Man Wing. Y.¹²³⁴,Rosair Georgina M.¹²³⁴,Welch Alan J.¹²³⁴

Affiliation:

1. Institute of Chemical Sciences

2. Heriot-Watt University

3. Edinburgh

4. UK EH14 4AS

Abstract

Nickelacarborane derivatives of 1,1′-bis(o-carborane) allow comment on the factors important in the isomerisation of metallacarboranes.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02855A

Reference43 articles.

1. The Preparation of 1-[1,2-Dicarbaclovododecaboranyl(12)]-1,2-dicarbaclovododecaborane(12)

2. Definitive crystal structure of 1,1′-bis[1,2-dicarba-closo-dodecaborane(11)]

3. Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane)

4. Metallocene compounds derived from .mu.-1,2-trimethylene-1,2-dicarba-closo-dodecaborane(10)

5. Reductive isomierization of icosahedral metallocarbaboranes

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