Transient absorption spectroscopy of the electron transfer step in the photochemically activated polymerizations of N-ethylcarbazole and 9-phenylcarbazole-Reference-Cited by-同舟云学术

Transient absorption spectroscopy of the electron transfer step in the photochemically activated polymerizations of N-ethylcarbazole and 9-phenylcarbazole

Published:2021 Issue:34 Volume:23 Page:18378-18392
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Thornton Georgia L.¹^ORCID,Phelps Ryan¹^ORCID,Orr-Ewing Andrew J.¹^ORCID

Affiliation:

1. School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK

Abstract

Transient absorption spectroscopy of electron transfer reactions between a carbazole and an iodonium salt reveals structure and solvent-dependent kinetic and mechanistic details important to initiation of polymerization.

Funder

FP7 Ideas: European Research Council

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03137F

Reference57 articles.

1. Photoinduced Step-Growth Polymerization of N-Ethylcarbazole

2. Photoinduced synthesis of poly(N-ethylcarbazole) from phenacylium salt without conventional catalyst and/or monomer