Two- and three-photon processes during photopolymerization in 3D laser printing

Author:

Mauri Anna1ORCID,Kiefer Pascal2ORCID,Neidinger Philipp34,Messer Tobias2,Bojanowski N. Maximilian1,Yang Liang12,Walden Sarah4,Unterreiner Andreas-Neil3ORCID,Barner-Kowollik Christopher14ORCID,Wegener Martin12,Wenzel Wolfgang1ORCID,Kozlowska Mariana1ORCID

Affiliation:

1. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany

2. Institute of Applied Physics (APH), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany

3. Institute of Physical Chemistry (IPC), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany

4. School of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George Street, Brisbane, QLD, 4000, Australia

Abstract

This study explores the mechanisms of photoactivation and radical formation during 3D laser printing using photoresists with a DETC photoinitiator. The role of DETC in high triplet states during radical polymerization is revealed.

Funder

Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg

Carl-Zeiss-Stiftung

Deutsche Forschungsgemeinschaft

Australian Research Council

Karlsruhe Institute of Technology

Publisher

Royal Society of Chemistry (RSC)

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