Direct observation of o-benzyne formation in photochemical hexadehydro-Diels–Alder (hν-HDDA) reactions-Reference-Cited by-同舟云学术

Direct observation of o-benzyne formation in photochemical hexadehydro-Diels–Alder (hν-HDDA) reactions

Published:2020 Issue:34 Volume:11 Page:9198-9208
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ma Xiaonan¹²³⁴⁵,Maier Jan⁶⁷²³⁴^ORCID,Wenzel Michael¹²³⁴,Friedrich Alexandra⁶⁷²³⁴^ORCID,Steffen Andreas⁶⁷²³⁴,Marder Todd B.⁶⁷²³⁴^ORCID,Mitrić Roland¹²³⁴^ORCID,Brixner Tobias¹²³⁴^ORCID

Affiliation:

1. Institut für Physikalische und Theoretische Chemie

2. Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Institute of Molecular Plus

6. Institut für Anorganische Chemie

7. Institute for Sustainable Chemistry & Catalysis with Boron

Abstract

We report the transient ultraviolet/visible absorption spectrum of an o-benzyne species in solution for the first time.

Funder

Deutsche Forschungsgemeinschaft

Julius-Maximilians-Universität Würzburg

FP7 Ideas: European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC03184D

Reference114 articles.

1. Synthesen in der hydroaromatischen Reihe

2. Thermolysis of 1,3,8-Nonatriyne: Evidence for Intramolecular [2 + 4] Cycloaromatization to a Benzyne Intermediate

3. Concerted vs Stepwise Mechanisms in Dehydro-Diels–Alder Reactions

4. New Thermal Routes to ortho-Benzyne

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. 4a Nucleophilic Aromatic Substitution;Organic Reaction Mechanisms Series;2024-03-15

2. Addition Reactions: Cycloaddition;Organic Reaction Mechanisms Series;2024-03-15

3. Ultrafast photophysics of para-substituted 2,5-bis(arylethynyl) rhodacyclopentadienes: thermally activated intersystem crossing;Chemical Science;2024

4. Programmable DNA Interstrand Crosslinking by Alkene–Alkyne [2 + 2] Photocycloaddition;Journal of the American Chemical Society;2023-04-18

5. Fused diethynylbenzenes and phenanthrenes via arynes with alkynylsilanes;Organic & Biomolecular Chemistry;2023