Ultrafast photophysics of <i>para</i>-substituted 2,5-bis(arylethynyl) rhodacyclopentadienes: thermally activated intersystem crossing-Reference-Cited by-同舟云学术

Ultrafast photophysics of para-substituted 2,5-bis(arylethynyl) rhodacyclopentadienes: thermally activated intersystem crossing

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guo Zilong¹^ORCID,Wang Yaxin¹,Heitmüller Julia²^ORCID,Sieck Carolin³,Prüfer Andreas⁴,Ralle Philipp⁴,Steffen Andreas⁴^ORCID,Henke Petr⁵⁶^ORCID,Ogilby Peter R.⁵^ORCID,Marder Todd B.³⁷^ORCID,Ma Xiaonan¹²^ORCID,Brixner Tobias²⁷^ORCID

Affiliation:

1. Institute of Molecular Plus, Tianjin University, Tianjin 300072, P. R. China

2. Institut für Physikalische und Theoretische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

3. Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

4. Department of Chemistry and Chemical Biology, TU Dortmund University, Otto-Hahn-Str. 6, 44227 Dortmund, Germany

5. Department of Chemistry, Aarhus University, Aarhus DK-8000, Denmark

6. Faculty of Science, Charles University, Hlavova 2030, 128 43 Prague 2, Czech Republic

7. Institute for Sustainable Chemistry and Catalysis with Boron (ICB), Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany

Abstract

Full photophysical picture and thermally activated ISC was revealed for rhodacyclopentadienes by fs-spectroscopy and Marcus analysis, while potential application on 1O2 sensitizing was explored.

Funder

National Key Research and Development Program of China

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC04306E

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