Synthesis, structure and bonding of actinide disulphide dications in the gas phase-Reference-Cited by-同舟云学术

Synthesis, structure and bonding of actinide disulphide dications in the gas phase

Published:2017 Issue:16 Volume:19 Page:10685-10694
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lucena Ana F.¹²³⁴⁵^ORCID,Bandeira Nuno A. G.⁶⁷⁸⁹¹⁰^ORCID,Pereira Cláudia C. L.¹²³⁴⁵^ORCID,Gibson John K.¹¹¹²¹³¹⁴,Marçalo Joaquim¹²³⁴⁵^ORCID

Affiliation:

1. Centro de Ciências e Tecnologias Nucleares

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 2695-066 Bobadela LRS

5. Portugal

6. Institute of Chemical Research of Catalonia (ICIQ)

7. Barcelona Institute of Technology (BIST)

8. 43007 Tarragona

9. Spain

10. Centro de Química Estrutural

11. Chemical Sciences Division

12. Lawrence Berkeley National Laboratory

13. Berkeley

14. USA

Abstract

CASPT2 computations reveal that gas-phase AnS₂²⁺ ions have ground states with triangular geometries and linear thio-actinyl structures are higher in energy, with a difference that increases upon moving from U to Pu.

Funder

Fundação para a Ciência e a Tecnologia

Basic Energy Sciences

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01446E

Reference44 articles.

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2. New Reactivity of the Uranyl(VI) Ion

3. Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds

4. Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges

5. Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures

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