Carbon–sulfur bond strength in methanesulfinate and benzenesulfinate ligands directs decomposition of Np(v) and Pu(v) coordination complexes-Reference-Cited by-同舟云学术

Carbon–sulfur bond strength in methanesulfinate and benzenesulfinate ligands directs decomposition of Np(v) and Pu(v) coordination complexes

Published:2020 Issue:10 Volume:49 Page:3293-3303
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vallet Valérie¹²³⁴⁵^ORCID,Gong Yu⁶⁷⁸⁹^ORCID,Saab Mohamad¹²³⁴⁵,Réal Florent¹²³⁴⁵^ORCID,Gibson John K.⁶⁷⁸⁹^ORCID

Affiliation:

1. Univ. Lille

2. CNRS

3. UMR 8523 – PhLAM – Physique des Lasers Atomes et Molécules

4. F-59000 Lille

5. France

6. Chemical Sciences Division

7. Lawrence Berkeley National Laboratory

8. Berkeley

9. USA

Abstract

Adjusting intra-ligand bond strengths in actinide sulfinate complexes directs towards alternative cleavage of carbon–sulfur or actinide–sulfinate bonds.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00125B

Reference35 articles.

1. Functionalization of C–H Bonds via Metal-Catalyzed Desulfitative Coupling: An Alternative Tool for Access to Aryl- or Alkyl-Substituted (Hetero)arenes

2. Gas Phase Studies of the Pesci Decarboxylation Reaction: Synthesis, Structure, and Unimolecular and Bimolecular Reactivity of Organometallic Ions

3. The 3D quadrupole ion trap mass spectrometer as a complete chemical laboratory for fundamental gas-phase studies of metal mediated chemistry

4. Determination of the relative ligand-binding strengths in heteroleptic IrIII complexes by ESI-Q-TOF tandem mass spectrometry

5. Transmetalation of Methyl Groups Supported by PtII–AuI Bonds in the Gas Phase, in Silico, and in Solution

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