Modulation of the FeII spin crossover effect in the pentadecanuclear {Fe9[M(CN)8]6} (M = Re, W) clusters by facial coordination of tridentate polyamine ligands
Author:
Affiliation:
1. Faculty of Chemistry
2. Jagiellonian University
3. 30-060 Krakow
4. Poland
5. Department of Chemistry
6. Marian Smoluchowski Institute of Physics
7. 30-348 Krakow
8. School of Science
9. The University of Tokyo
10. Tokyo 113-0033
11. Japan
Abstract
N,N,N-tridentate ligands coordinated to {Fe9[M(CN)8]6} (M = Re, W) induce the spin crossover on the external Fe sites of the cluster.
Funder
Japan Society for the Promotion of Science
Narodowe Centrum Nauki
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01416C
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2. J.-F. Létard , P.Guionneau and L.Goux-Capes, in Spin Crossover in Transition Metal Compounds I–III, ed. P. Gütlich and H. Goodwin, Springer, Berlin/Heidelberg, 2004, pp. 221–249
3. Tunable Bistability in a Three-Dimensional Spin-Crossover Sensory- and Memory-Functional Material
4. Pressure and Temperature Spin Crossover Sensors with Optical Detection
5. Spin state switching in iron coordination compounds
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