Mixed-valence di-ruthenium(ii,iii) complexes of redox non-innocent N-aryl-o-phenylenediamine derivatives
Author:
Affiliation:
1. Department of Chemistry
2. Ramakrishna Mission Residential College (Autonomous)
3. Kolkata – 700103
4. India
Abstract
The importance of the existence of both redox-innocent and non-innocent coordination sites in a ligand in modelling mixed-valence di-ruthenium(ii,iii) complexes is disclosed.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00779C
Reference61 articles.
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3. Electronic Structures of Ruthenium and Osmium Complexes of 9,10-Phenanthrenequinone
4. Redox-active ligands in catalysis
5. Storing redox equivalent in the phenalenyl backbone towards catalytic multi-electron reduction
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1. Mixed-valence outer-sphere RuII/RuIII ion-pair complexes. Synthesis, experimental, and theoretical studies;Polyhedron;2022-09
2. Structural and electronic forms of doubly oxido/Pz and triply oxido/(Pz)2 bridged mixed valent and isovalent diruthenium complexes (Pz = pyrazolate);Dalton Transactions;2021
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