Structural and electronic forms of doubly oxido/Pz and triply oxido/(Pz)2 bridged mixed valent and isovalent diruthenium complexes (Pz = pyrazolate)-Reference-Cited by-同舟云学术

Structural and electronic forms of doubly oxido/Pz and triply oxido/(Pz)2 bridged mixed valent and isovalent diruthenium complexes (Pz = pyrazolate)

Published:2021 Issue:47 Volume:50 Page:17653-17664
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bera Sudip Kumar¹,Lahiri Goutam Kumar¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, India

Abstract

Oxido/Pz and oxido/(Pz)2 bridged RuIII RuIV and RuIIRuIII mixed valent states in diastereomeric meso-1/rac-2 and 3+, respectively, exhibited a delocalised class III situation with calculated electronic coupling parameter (Vab) of ≈ 4000 cm−1.

Funder

Science and Engineering Research Board

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03076K

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5. Three Distinct Redox States of an Oxo-Bridged Dinuclear Ruthenium Complex

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