Structural, magnetic and theoretical analyses of anionic and cationic phthalocyaninato-terbium(iii) double-decker complexes: magnetic relaxation via higher ligand-field sublevels enhanced by oxidation-Reference-Cited by-同舟云学术

Structural, magnetic and theoretical analyses of anionic and cationic phthalocyaninato-terbium(iii) double-decker complexes: magnetic relaxation via higher ligand-field sublevels enhanced by oxidation

Published:2021 Issue:28 Volume:50 Page:9719-9724
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Horii Yoji¹²³⁴⁵^ORCID,Damjanović Marko⁶⁷⁸⁹,Katoh Keiichi¹¹⁰¹¹¹²⁵^ORCID,Yamashita Masahiro¹¹⁰¹³¹⁴¹⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Nara Women's University

4. Nara 630-8506

5. Japan

6. Institute of Inorganic Chemistry

7. Heidelberg University Im Neuenheimer Feld 270

8. 69120 Heidelberg

9. Germany

10. Graduate School of Science

11. Josai University

12. Saitama 350-0295

13. Tohoku University

14. Sendai

15. Miyagi 980-8578

Abstract

Ligand oxidation of single-molecule magnets enhances magnetic relaxations via higher energy levels.

Funder

Higher Education Discipline Innovation Project

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00775K

Reference31 articles.

1. Metal Bisporphyrinate Double-Decker Complexes as Redox-Responsive Rotating Modules. Studies on Ligand Rotation Activities of the Reduced and Oxidized Forms Using Chirality as a Probe

2. A new series of molecular semiconductors: phthalocyanine radicals

3. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level

4. A theoretical study of a drastic structural change of bis(phthalocyaninato)lanthanide by ligand oxidation: Towards control of ligand field strength and magnetism of single-lanthanide-ionic single molecule magnet

5. Redox‐Driven Symmetry Change for Terbium(III) Bis(porphyrinato) Double‐Decker Complexes by the Azimuthal Rotation of the Porphyrin Macrocycles

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