Interplay between anisotropy and magnetic exchange to modulate the magnetic relaxation behaviours of phenoxo bridged Dy<sub>2</sub> dimers with axial β-diketonate co-ligands-Reference-Cited by-同舟云学术

Interplay between anisotropy and magnetic exchange to modulate the magnetic relaxation behaviours of phenoxo bridged Dy₂ dimers with axial β-diketonate co-ligands

Published:2022 Issue:47 Volume:51 Page:18187-18202
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Roy Soumalya¹,Shukla Pooja¹,Ahmed Naushad²^ORCID,Du Ming-Hao³,Tarannum Ibtesham²,Kong Xiang-Jian³^ORCID,Gupta Tulika⁴,Singh Saurabh Kumar²^ORCID,Das Sourav¹^ORCID

Affiliation:

1. Department of Basic Sciences, Chemistry Discipline, Institute of Infrastructure Technology Research And Management, Near Khokhra Circle, Maninagar East, Ahmedabad-380026, Gujarat, India

2. Indian Institute of Technology Hyderabad, Kandi, Telangana 502285, India

3. State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China

4. Department of Chemistry, Institute of Science, BHU, Varanasi-221005, UP, India

Abstract

According to this study, the magnetic exchange and anisotropy of Dy2 complexes 1–3 were changed by axial-diketonate co-ligands, which controlled the SMM behaviors. Anisotropy of DyIII sites and barriers amended while JDy-Dy strength decreased in 1–3.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT03117E

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1. Enhancing coherence in molecular spin qubits via atomic clock transitions