A hexagon based Mn(ii) rod metal–organic framework – structure, SF6gas sorption, magnetism and electrochemistry

Author:

Amombo Noa Francoise M.1ORCID,Cheung Ocean2ORCID,Åhlén Michelle2,Ahlberg Elisabet3ORCID,Nehla Priyanka2,Salazar-Alvarez Germán2ORCID,Ershadrad Soheil4,Sanyal Biplab4ORCID,Öhrström Lars1ORCID

Affiliation:

1. Chemistry and Biochemistry, Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg SE-41296, Sweden

2. Department of Materials Science and Engineering, Ångström Laboratory, Uppsala University, Uppsala SE-751 03, Sweden

3. Department of Chemistry & Molecular Biology, University of Gothenburg, Gothenburg 405 30, Sweden

4. Department of Physics & Astronomy, Uppsala University, Box-516, Uppsala 75120, Sweden

Abstract

Made from hexagon linkers and Mn(ii) the MOF CTH-18 shows high uptake of the 22 000-times-stronger-than-CO2greenhouse gas SF6at 0.1 bar, a pressure practically relevant for industrial SF6sorbents, combined with relatively fast kinetics.

Funder

Vetenskapsrådet

Svenska Forskningsrådet Formas

Stiftelsen Olle Engkvist Byggmästare

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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