Hydrogen bond, ring tension and π-conjugation effects: methyl and vinyl substitutions dramatically change the photodynamics of Criegee intermediates
Author:
Affiliation:
1. Key Laboratory for Macromolecular Science of Shaanxi Province
2. School of Chemistry & Chemical Engineering
3. Shaanxi Normal University
4. Xi’an
5. P. R. China
Abstract
Dramatic substitution effects by saturated and unsaturated substituents on the photodynamics of Criegee intermediates.
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP01873B
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1. Mechanism of Ozonolysis
2. Kinetic and Theoretical Investigation of the Gas-Phase Ozonolysis of Isoprene: Carbonyl Oxides as an Important Source for OH Radicals in the Atmosphere
3. Direct Kinetic Measurements of Criegee Intermediate (CH 2 OO) Formed by Reaction of CH 2 I with O 2
4. Extremely rapid self-reaction of the simplest Criegee intermediate CH2OO and its implications in atmospheric chemistry
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