Field-induced magnetic relaxation in heteropolynuclear Ln<sup>III</sup>/Zn<sup>II</sup> metal organic frameworks: cerium and dysprosium cases-Reference-Cited by-同舟云学术

Field-induced magnetic relaxation in heteropolynuclear Ln^III/Zn^II metal organic frameworks: cerium and dysprosium cases

Published:2023 Issue:47 Volume:47 Page:21781-21789
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

López Agustín¹^ORCID,Cruz Carlos²³^ORCID,Paredes-García Verónica²³^ORCID,Veiga Nicolás¹^ORCID,Lloret Francesc⁴,Torres Julia¹^ORCID,Chiozzone Raúl¹^ORCID

Affiliation:

1. Facultad de Química, Área Química Inorgánica, Universidad de la República, Montevideo, Uruguay

2. Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Universidad Andrés Bello, Santiago, Chile

3. Center for the Development of Nanoscience and Nanotechnology, Cedenna, Chile

4. Instituto de Ciencia Molecular (ICMol), Universitat de València, Valencia, Spain

Abstract

The MOF [Ce2Zn3(oda)6(H2O)6]·12H2O displays field-induced slow magnetic relaxation and phonon-bottleneck effect. Ab initio calculations reveal strong mixing of spin–orbit levels in the CeIII ground state and significant tunneling probability.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ03774F

Reference72 articles.

1. Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level

2. Single-Ion Magnets with Giant Magnetic Anisotropy and Zero-Field Splitting

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4. A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit

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