New insights into the breathing phenomenon in ZIF-4-Reference-Cited by-同舟云学术

New insights into the breathing phenomenon in ZIF-4

Published:2019 Issue:24 Volume:7 Page:14552-14558
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Gandara-Loe Jesus¹²³⁴⁵,Missyul Alexander⁶⁷⁵^ORCID,Fauth François⁶⁷⁵^ORCID,Daemen Luke L.⁸⁹¹⁰¹¹,Cheng Yongqiang Q.⁸⁹¹⁰¹¹^ORCID,Ramirez-Cuesta Anibal J.⁸⁹¹⁰¹¹^ORCID,Ravikovitch Peter I.¹²¹³¹¹,Silvestre-Albero Joaquin¹²³⁴⁵^ORCID

Affiliation:

1. Laboratorio de Materiales Avanzados

2. Departamento de Química Inorgánica-IUMA

3. Universidad de Alicante

4. E-03690 San Vicente Del Raspeig

5. Spain

6. CELLS-ALBA Syncrotron

7. E-08290 Cerdanyola Del Vallés

8. Oak Ridge National Laboratory

9. Spallation Neutron Source

10. Oak Ridge

11. USA

12. ExxonMobil Research and Engineering Co.

13. Annandale

Abstract

The pufferfish effect in ZIF-4: synchrotron X-ray powder diffraction studies under operando conditions confirm that ZIF-4 experiences a breathing phenomenon above ∼30 kPa associated with a large expansion in the unit cell volume (∼8–9%). The presence of an expanded-pore (N₂) ZIF-4 structure is predicted by molecular simulations.

Funder

Generalitat Valenciana

Ministerio de Economía y Competitividad

Horizon 2020 Framework Programme

Laboratory Directed Research and Development

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/TA/C8TA09713E

Reference15 articles.