Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering-Reference-Cited by-同舟云学术

Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering

Published:2016 Issue:18 Volume:52 Page:3639-3642
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Casco M. E.¹²³⁴,Cheng Y. Q.⁵⁶⁷⁸,Daemen L. L.⁵⁶⁷⁸,Fairen-Jimenez D.⁹¹⁰¹¹¹²^ORCID,Ramos-Fernández E. V.¹²³⁴,Ramirez-Cuesta A. J.⁵⁶⁷⁸,Silvestre-Albero J.¹²³⁴

Affiliation:

1. Laboratorio de Materiales Avanzados

2. Departamento de Química Inorgánica-Instituto Universitario de Materiales

3. Universidad de Alicante

4. Spain

5. Oak Ridge National Laboratory

6. Chemical and Engineering Materials Division

7. Oak Ridge

8. USA

9. Department of Chemical Engineering and Biotechnology

10. University of Cambridge

11. Cambridge CB2 3RA

12. UK

Abstract

Gate-opening effect. Inelastic neutron scattering experiments show that nitrogen exposure induces the swinging of the –CH₃ groups and the imidazolate linkers in ZIF-8, this being the origin of the gate-opening effect.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC10222G

Reference14 articles.

1. Dynamic porous properties of coordination polymers inspired by hydrogen bonds

2. Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences

3. Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations

4. Understanding Gas-Induced Structural Deformation of ZIF-8

5. The Effect of Pressure on ZIF-8: Increasing Pore Size with Pressure and the Formation of a High-Pressure Phase at 1.47 GPa

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