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A tendril perversion in a helical oligomer: trapping and characterizing a mobile screw-sense reversal

  • Published:2017 Issue:4 Volume:8 Page:3007-3018
  • ISSN:2041-6520
  • Container-title:Chemical Science
  • language:en
  • Short-container-title:Chem. Sci.

Author:

Tomsett Michael1234,Maffucci Irene5678,Le Bailly Bryden A. F.1234,Byrne Liam19104,Bijvoets Stefan M.19104,Lizio M. Giovanna1910411,Raftery James19104,Butts Craig P.1234ORCID,Webb Simon J.1910411ORCID,Contini Alessandro5678ORCID,Clayden Jonathan1234ORCID

Affiliation:

1. School of Chemistry

2. University of Bristol

3. Bristol BS8 1TS

4. UK

5. Dipartimento di Scienze Farmaceutiche − Sezione di Chimica Generale e Organica “Alessandro Marchesini”

6. Università degli Studi di Milano

7. 21 20133 Milano

8. Italy

9. University of Manchester

10. Manchester M13 9PL

11. Manchester Institute of Biotechnology

Abstract

Inducing opposite screw senses at the two ends of a helix traps a helix reversal, allowing it to be characterised spectroscopically.

Funder

H2020 European Research Council

Engineering and Physical Sciences Research Council

Biotechnology and Biological Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference89 articles.

1. C. McManus , Right Hand, Left Hand, Harvard University Press, 2003

2. Helices

3. C. Darwin , The movements and habits of climbing plants, 1882

4. Spontaneous Helix Hand Reversal and Tendril Perversion in Climbing Plants

5. Tendril Perversion in Intrinsically Curved Rods

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