Quantitative electronic structure and work-function changes of liquid water induced by solute-Reference-Cited by-同舟云学术

Quantitative electronic structure and work-function changes of liquid water induced by solute

Published:2022 Issue:3 Volume:24 Page:1310-1325
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Credidio Bruno¹²^ORCID,Pugini Michele¹^ORCID,Malerz Sebastian¹^ORCID,Trinter Florian¹³^ORCID,Hergenhahn Uwe¹^ORCID,Wilkinson Iain⁴^ORCID,Thürmer Stephan⁵^ORCID,Winter Bernd¹^ORCID

Affiliation:

1. Molecular Physics Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany

2. Institute for Chemical Sciences and Engineering (ISIC), École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland

3. Institut für Kernphysik, Goethe-Universität, Max-von-Laue-Straße 1, 60438 Frankfurt am Main, Germany

4. Department of Locally-Sensitive & Time-Resolved Spectroscopy, Helmholtz-Zentrum Berlin für Materialien und Energie, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

5. Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-Ku, Kyoto 606-8502, Japan

Abstract

Significant differences are observed in liquid-water's lowest electron binding energy with increasing solute concentration in archetypal aqueous solutions. For NaI(aq) and TBAI(aq), the energy changes extend to +0.3 eV and −0.7 eV, respectively.

Funder

Deutsche Forschungsgemeinschaft

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

H2020 European Research Council

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP03165A

Reference54 articles.